| 1970 | Songs of the Sea | Benjamin Luxon and the Climax Male Voice Choir | | 1 |
| 1972 | Benjamin Luxon Sings Mussorgsky | Mussorgsky, Benjamin Luxon, David Willison | | 1 |
| 1976 | Home, Sweet Home: Victorian Songs and Ballads, Volume 2 | Robert Tear, Benjamin Luxon & André Previn | | 2 |
| 1976 | Messe de Requiem op. 48 / Cantique de Jean Racine op. 11 | Fauré; Benjamin Luxon, Jonathon Bond, The Choir of St John’s College, Cambridge, The Academy of St. Martin in the Fields, George Guest | | 1 |
| 1978 | Mariazeller Mass / Little Organ Mass | Haydn; Jennifer Smith, Helen Watts, Robert Tear, Benjamin Luxon, Choir of St. John’s College, Cambridge, John Scott, Academy of St. Martin-in-the-Fields, George Guest | | 1 |
| 1982 | Große Messe C-Moll | Mozart; Barbara Hendricks, Janet Perry, Peter Schreier, Benjamin Luxon, Wiener Singverein, Berliner Philharmoniker, Herbert von Karajan | | 5 |
| 1987 | Two Gentlemen Folk | Benjamin Luxon, Bill Crofut & Friends | | 1 |
| 1988 | Songs | Sir Edward Elgar, Frederick Delius; Benjamin Luxon, David Willison | | 1 |
| 1988 | Warlock Songs | Peter Warlock; Benjamin Luxon, David Willison | | 1 |
| 1989 | Die tote Stadt | Erich Wolfgang Korngold; Erich Leinsdorf, Carol Neblett, René Kollo, Hermann Prey, Benjamin Luxon, Münchner Rundfunkorchester, Chor des Bayerischen Rundfunks | | 2 |
| 1989 | Sings Folk Songs At Tanglewood & Simple Gifts | Benjamin Luxon & Bill Crofut | | 1 |
| 1992 | British Composers: A Mass of Life / Songs of Sunset / An Arabesque | Delius; Heather Harper, Helen Watts, Robert Tear, Benjamin Luxon, Dame Janet Baker, John Shirley‐Quirk, Royal Liverpool Philharmonic Choir, London Philharmonic Choir, Royal Liverpool Philharmonic Orchestra, London Philharmonic Orchestra, Sir Charles Groves | | 1 |
| 1992 | Messiah | Handel; James Bowman, Robert Tear, Benjamin Luxon, Choir of King’s College, Cambridge, Academy of St Martin in the Fields, Sir David Willcocks | | 1 |
| 1994 | The Kingdom | Elgar; Yvonne Kenny, Alfreda Hodgson, Christopher Gillett, Benjamin Luxon, London Philharmonic Orchestra and Choir, Leonard Slatkin | | 1 |
| 1997 | The Last Night of the Proms | Peter Donohoe, Benjamin Luxon, BBC Singers, BBC Symphony Chorus, BBC Symphony Orchestra, James Loughran | | 1 |
| 2006 | Miss Julie | William Alwyn; Jill Gomez, Benjamin Luxon, Della Jones, John Mitchinson, Philharmonia Orchestra, Vilém Tauský | | 1 |
| 2006 | L'Incontro Improvviso | Haydn; Zoghby, Marshall, Jones, Claes H. Ahnsjö, Trimarchi, Luxon, Antal Doráti, Orchestre de Chambre de Lausanne | | 1 |
| 2007 | John Ireland: The Complete Songs | John Ireland; Alfreda Hodgson, Benjamin Luxon, John Mitchinson,Alan Rowlands | | 1 |
| 2024 | Songs of the Sea / Songs of the Fleet / Symphony No. 3 "Irish" | Stanford; Benjamin Luxon, Norman Del Mar, Bournemouth Symphony Orchestra, Bournemouth Sinfonietta | | 1 |
| — | Owen Wingrave | Britten; Benjamin Luxon, John Shirley‐Quirk, Nigel Douglas, Sylvia Fisher, Jennifer Vyvyan, Janet Baker, Peter Pears, English Chamber Orchestra, Benjamin Britten | 1 | 1 |
| — | The Notebook of Anna Magdalena Bach | Igor Kipnis, Judith Blegen, Benjamin Luxon, Catharina Meints | | 1 |
| — | The Dream of Gerontius | Edward Elgar; Robert Tear, Alfreda Hodgson, Benjamin Luxon, The Scottish National Orchestra Chorus, Scottish National Orchestra, Sir Alexander Gibson | | 1 |
