| 1983 | Capriccio espagnol / May Night Overture / Sadko / Snow Maiden Suite | Rimksy-Korsakov; Roberta Alexander, Rotterdam Philharmonic Orchestra, David Zinman | | 1 |
| 1984 | Symphony no. 4 | Mahler; Roberta Alexander, Concertgebouw Orchestra, Amsterdam, Bernard Haitink | | 2 |
| 1987 | Puccini Songs & Other Rare Pieces | Giacomo Puccini; Roberta Alexander, Tan Crone, Raphael String Quartet | | 1 |
| 1989 | Don Giovanni | Mozart; Hampson, Alexander, Bonney, Blochwitz, Polgár, Scharinger, Holl, Royal Concertgebouw Orchestra Amsterdam, Harnoncourt | | 3 |
| 1990 | Da Capo: Die Teldec Klassik Edition, Folge 1: Arien und Chöre | Wolfgang Amadeus Mozart; Edita Gruberová, Yvonne Kenny, Roberta Alexander, Peter Schreier, Anton Scharinger, Thomas Hampson, Royal Concertgebouw Orchester, Nikolaus Harnoncourt | | 1 |
| 1993 | Roberta Alexander sings Samuel Barber | Roberta Alexander, Edo de Waart & Radio Filharmonisch Orkest | | 1 |
| 1994 | Mass In B Minor | Bach; Ruth Ziesak, Roberta Alexander, Jard van Nes, Keith Lewis, David Wilson‐Johnson, Symphonieorchester des Bayerischen Rundfunks, Chor des Bayerischen Rundfunks, Carlo Maria Giulini | | 1 |
| 1994 | Der gewaltige Hahnrei / Mediterranean Songs | Berthold Goldschmidt; Alexander, Kraus, Wörle, Otelli, Deutsches Symphonie‐Orchester Berlin, Ainsley, Gewandhausorchester Leipzig, Lothar Zagrosek | | 1 |
| 1995 | Apollo e Dafne | Händel; Roberta Alexander, Thomas Hampson, Concentus Musicus Wien, Harnoncourt | | 1 |
| 1998 | Händel: Apollo e Dafne / Telemann: Ino | Händel, Telemann; Roberta Alexander, Thomas Hampson, Concentus Musicus Wien, Nikolaus Harnoncourt | | 1 |
| 1999 | Theodora | George Frideric Handel; Roberta Alexander, Hans Peter Blochwitz, Jochen Kowalski, Jard van Nes, Anton Scharinger, Arnold Schoenberg Chor, Concentus Musicus Wien, Nikolaus Harnoncourt | | 1 |
| 2021 | Miroir de peine: Orchestral Music & Concertos | Hendrik Andriessen; Roberta Alexander, Netherlands Radio Chamber Orchestra, David Porcelijn, Thierry Fischer | | 1 |
| — | Porgy and Bess (highlights) | George Gershwin; Simon Estes, Roberta Alexander, Rundfunk-Sinfonieorchester Berlin, Leonard Slatkin | | 2 |
