| 1967 | A Richard Strauss Song Recital | Richard Strauss; Montserrat Caballé, Miguel Zanetti | | 1 |
| 1968 | Zarzuela Love Duets | Montserrat Caballé, Bernabé Martí | | 1 |
| 1970 | Monsterrat Caballé: Puccini Arias | Puccini; Montserrat Caballé, London Symphony Orchestra, Charles Mackerras | | 3 |
| 1971 | Il pirata | Vincenzo Bellini; Montserrat Caballé, Bernabé Martí, Piero Cappuccilli, Ruggero Raimondi, Orchestra e Coro della Radiotelevisione Italiana, Roma, Gianandrea Gavazzeni | | 2 |
| 1973 | Giovanna d’Arco | Giuseppe Verdi; Montserrat Caballé, Plácido Domingo, Sherrill Milnes, London Symphony Orchestra, Ambrosian Opera Chorus, James Levine | 5 | 3 |
| 1973 | Norma | Vincenzo Bellini; Montserrat Caballé, Fiorenza Cossotto, Plácido Domingo, Ruggero Raimondi, London Philharmonic Orchestra, Carlo Felice Cillario | 5 | 3 |
| 1973 | Turandot | Puccini; Sutherland, Pavarotti, Caballé, Ghiaurov, Krause, Pears, John Alldis Choir, London Philharmonic Orchestra, Zubin Mehta | | 5 |
| 1974 | Aida | Giuseppe Verdi; Montserrat Caballé, Plácido Domingo, Chorus of the Royal Opera House, Covent Garden, New Philharmonia Orchestra, Riccardo Muti | | 13 |
| 1975 | Presenting Montserrat Caballe | Montserrat Caballé | | 1 |
| 1977 | Debussy: La Damoiselle Elue / Chausson: Poème de L'Amour et de la Mer [Caballé] | Claude Debussy; Ernest Chausson; Montserrat Caballé, Wyn Morris, Symphonica of London & Janet Coster | | 3 |
| 1978 | Verdi Favorites | Montserrat Caballé | | 1 |
| 1980 | I puritani | Vincenzo Bellini; Montserrat Caballé, Alfredo Kraus, Julia Hamari, Matteo Manuguerra, Agostino Ferrin, Ambrosian Opera Chorus, Philharmonia Orchestra, Riccardo Muti | | 4 |
| 1982 | Il turco in Italia | Rossini; Samuel Ramey, Montserrat Caballé, Leo Nucci, Enzo Dara, Ernesto Palacio, Paulo Barbacini, Jane Berbié, National Philharmonic Orchestra, Ambrosian Opera Chorus, Riccardo Chailly | | 3 |
| 1984 | Andrea Chénier | Umberto Giordano; Luciano Pavarotti, Montserrat Caballé, Leo Nucci, National Philharmonic Orchestra, Riccardo Chailly | | 1 |
| 1985 | Mefistofele | Arrigo Boito; Nicolaï Ghiaurov, Luciano Pavarotti, Mirella Freni, Montserrat Caballé, National Philharmonic Orchestra, Oliviero de Fabritiis | | 1 |
| 1986 | Tosca | Puccini; Montserrat Caballé, José Carreras, Ingvar Wixell, Orchestra & Chorus of the Royal Opera House, Covent Garden, Sir Colin Davis | | 7 |
| 1987 | Cançó d'amor i de guerra | Rafael Martínez Valls;Montserrat Caballé,Vicens Sardinero,Josep Ma. Carreras,Orquestra Simfònica de Barcelona,Antoni Ros‐Marbà | | 1 |
| 1988 | Barcelona | Freddie Mercury & Montserrat Caballé | 4.55 | 16 |
| 1988 | Luisa Miller | Verdi; Pavarotti, Caballé, Milnes, Giaiotti, Reynolds, van Allan, National Philharmonic, Maag | | 3 |
| 1988 | Norma | Vincenzo Bellini; Orchestra and Chorus of the Welsh National Opera, Richard Bonynge, Joan Sutherland, Luciano Pavarotti, Montserrat Caballé, Samuel Ramey | | 1 |
| 1989 | Don Carlo | Giuseppe Verdi; Plácido Domingo, Montserrat Caballé, Ruggero Raimondi, Shirley Verrett, Sherrill Milnes, Giovanni Foiani, Simon Estes, Ambrosian Opera Chorus, Orchestra of the Royal Opera House, Covent Garden, Carlo Maria Giulini | | 6 |
| 1989 | Salome | Strauss; Montserrat Caballé, Sherrill Milnes, Richard Lewis, Regina Resnik, James King, London Symphony Orchestra, Erich Leinsdorf | | 2 |
| 1989 | Il Corsaro | Verdi; Caballé, Norman, Carreras, New Philharmonia Orchestra, Lamberto Gardelli | | 2 |
| 1989 | I masnadieri | Giuseppe Verdi; Montserrat Caballé, Carlo Bergonzi, Piero Cappuccilli, Ruggero Raimondi, Ambrosian Singers, New Philharmonia Orchestra, Lamberto Gardelli | | 1 |
| 1989 | Lucrezia Borgia | Gaetano Donizetti; Montserrat Caballé, Shirley Verrett, Alfredo Kraus, Ezio Flagello, Jonel Perlea | | 3 |
| 1990 | Cantate : Clovis et Clotilde / Symphonie “Roma” | Bizet; M. Caballé, G. Garino, B. Martinovich, Orchestre national de Lille, Jean‐Claude Casadesus | | 2 |
| 1990 | La bohème | Giacomo Puccini; Montserrat Caballé, Plácido Domingo, Sherrill Milnes, Judith Blegen, Vicente Sardinero, Ruggero Raimondi, The John Alldis Choir, London Philharmonic Orchestra, Georg Solti | | 5 |
| 1990 | Un ballo in maschera | Verdi; Montserrat Caballé, José Carreras, Ingvar Wixell, Patricia Payne, Royal Opera House, Covent Garden, Sir Colin Davis | | 2 |
| 1991 | Grandes intérpretes - Arias | Montserrat Caballé | | 1 |
| 1992 | From the Official Barcelona Games Ceremony | Domingo, Carreras, Caballé with Aragall, Berganza, Pons | | 3 |
| 1992 | The Collection | Montserrat Caballé | | 1 |
| 1993 | Grandes Cantantes Líricos Españoles | José Carreras, Montserrat Caballé, Plácido Domingo, Teresa Berganza, Alfredo Kraus & Pilar Lorengar | | 1 |
| 1993 | Mascagni: Cavalleria rusticana / Leoncavallo: I Pagliacci | Pietro Mascagni, Ruggero Leoncavallo; Montserrat Caballé, José Carreras, Matteo Manuguerra, Julia Hamari, Astrid Varnay, Renata Scotto, Ugo Benelli, Sir Thomas Allen, Leslie Fyson, Kari Nurmela | | 2 |
| 1994 | Hijo de la luna | Montserrat Caballé | | 1 |
| 1994 | Manon Lescaut | Giacomo Puccini; Montserrat Caballé, Plácido Domingo, Noel Mangin, Vicente Sardinero, Bruno Bartoletti | | 2 |
| 1995 | Two Voices One Heart-1993 | Montserrat Caballé | | 2 |
| 1995 | Faust (Extraits) | Charles Gounod; Montserrat Caballé, Giacomo Aragall | | 1 |
| 1995 | Grandi Voci | Montserrat Caballé | | 1 |
| 1995 | Lucia di Lammermoor | Gaetano Donizetti; Montserrat Caballé, José Carreras, Samuel Ramey, Ambrosian Opera Chorus, New Philharmonia Orchestra, Jesús López-Cobos | | 2 |
| 1996 | Bernstein Conducts Bernstein: Chichester Psalms / Symphony no. 3 "Kaddish" | Bernstein; Wiener Jeunesse-Chor, Vienna Boy's Choir, Israel Philharmonic Orchestra, Leonard Bernstein, Montserrat Caballé, Michael Wager | | 1 |
| 1996 | Our Christmas Songs | Montserrat Caballé & Montserrat Martí | | 2 |
| 1997 | Pagliacci | Leoncavallo; Plácido Domingo, Montserrat Caballé, Sherrill Milnes, Barry McDaniel, The John Alldis Choir, London Symphony Orchestra, Nello Santi | | 1 |
| 1997 | Friends for Life | Montserrat Caballé | | 1 |
| 1997 | Mefistofele | Boito; Treigle, Domingo, Caballé, Ambrosian Opera Chorus, London Symphony Orchestra, Julius Rudel | | 1 |
| 1998 | Eloquence - Ein Abend mit Montserrat Caballe | Montserrat Caballé | | 1 |
| 1998 | Guillaume Tell | Gioachino Rossini; Gabriel Bacquier, Montserrat Caballé, Nicolai Gedda, Mady Mesplé, Kolos Kovacs, Gwynne Howell, Ambrosian Opera Chorus, Royal Philharmonic Orchestra, Lamberto Gardelli | 5 | 3 |
| 1998 | Mascagni: Cavalleria rusticana / Leoncavallo: Pagliacci | Mascagni, Leoncavallo; Montserrat Caballé, José Carreras, Renata Scotto, Ambrosian Opera Chorus & Philharmonia Orchestra, Riccardo Muti | | 3 |
| 1999 | La Gioconda | Ponchielli; Montserrat Caballé, José Carreras, Matteo Manuguerra, Jesús López Cobos | | 1 |
| 1999 | La Gioconda | Amilcare Ponchielli; Montserrat Caballé, Luciano Pavarotti, Agnes Baltsa, Alfreda Hodgson, Sherrill Milnes, John del Carlo, Nicolai Ghiaurov, Neil Jenkins, Stephen Varcoe, Geoffrey Shaw, Rodney Macann; National Philharmonic Orchestra, London Opera Chorus, Bruno Bartoletti | | 2 |
| 1999 | La traviata | Giuseppe Verdi; Montserrat Caballé, Carlo Bergonzi, Sherrill Milnes, Dorothy Krebill, RCA Italiana Opera Orchestra & Chorus, Georges Prêtre | | 1 |
| 1999 | Roberto Devereux | Gaetano Donizetti; Montserrat Caballé; José Carreras; Julius Rudel | | 1 |
| 2001 | Songs of the Spanish Renaissance, Vol. 1 | Montserrat Caballé | | 3 |
| 2005 | Mefistofele | Arrigo Boito; Nicolaï Ghiaurov, Luciano Pavarotti, Mirella Freni, Montserrat Caballé, National Philharmonic Orchestra, Oliviero de Fabritiis | 5 | 1 |
| 2006 | Strauss: Scenes from “Salome“ / 5 Lieder / Boito: Prologue from “Mefistofele” | R. Strauss, Boito; Montserrat Caballé, Nicolaï Ghiaurov, Leonard Bernstein | | 2 |
| 2006 | Montserrat Caballé - French Opera Arias | Montserrat Caballé | | 1 |
| 2009 | Cristóbal Colón | Leonardo Balada; José Carreras, Montserrat Caballé, Orchestra and Chorus of the Gran Teatre del Liceu, Barcelona, Theo Alcántara | | 1 |
| 2014 | Salome | Strauss, Caballé, Leinsdorf, London Symphony Orchestra | | 1 |
| 2017 | Gemma di Vergy | Donizetti; Montserrat Caballé, Paul Plishka, Luis Lima, Louis Quilico, Schola Cantorum, Opera Orchestra Of New York, Eve Queler | | 1 |
| — | Adriana Lecouvreur | Cilea; Montserrat Caballe, Jose Carreras, Gianfranco Masini | | 1 |
| — | Donizetti Rarities | Donizetti; Montserrat Caballé | | 1 |
| — | In mir klingt ein Lied | Montserrat Caballé | | 1 |
